Unit | Topic | Sub-topics |
Unit 1 | Solid State | Classification of solids based on different binding forces; molecular, ionic covalent and metallic solids, amorphous and crystalline solids (elementary idea), unit cell in two dimensional and three-dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids, number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties, Band theory of metals, conductors, semiconductors and insulators. |
Unit 2 | Solutions | Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, colligative properties- relative lowering of vapour pressure, Raoult’s law, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties abnormal molecular mass. Van Hoff factor. |
Unit 3 | Electrochemistry | Redox reactions, conductance in electrolytic solutions, specific and molar conductivity variation of conductivity with concentration, kohlrausch’s Law, electrolysis and Laws of electrolysis (elementary idea), dry cell- electrolytic cells and Galvanic cells; lead accumulator, EMF of a cell, standard electrode potential, Relation between Gibbs energy change and EMF of a cell, fuel cells; corrosion |
Unit 4 | Chemical Kinetics | Rate of a reaction (average and instantaneous), factors affecting rates of reaction; concentration, temperature, catalyst; order and molecularity of a reaction; rate law and specific rate constant, integrated rate equations and half life (only for zero and first order reactions); concept of collision theory ( elementary idea, no mathematical treatment). Activation energy, Arrhenious equation |
Unit 5 | Surface Chemistry | Adsorption-physisorption and chemisorption; factors affecting adsorption of gases on solids, catalysis homogeneous and heterogeneous, activity and selectivity: enzyme catalysis; colloidal state: distinction between true solutions, colloids and suspensions; lyophillic, lyophobic multimolecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement, electrophoresis, coagulation; emulsions- types of emulsions |
Unit 6 | General Principles and Processes of Isolation of Elements | Principles and methods of extraction- concentration, oxidation, reduction electrolytic method and refining; occurrence and principles of extraction of aluminium, copper, zinc and iron |
Unit 7 | p- Block Elements | - Group 15 elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; preparation and properties of ammonia and nitric acid, oxides of nitrogen (structure only); Phosphorous- allotropic forms; compounds of phosphorous: preparation and properties of phosphine, halides (PCI3, PCI5) and oxoacids (elementary idea only)
- Group 16 elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; dioxygen: preparation, properties and uses; classification of oxides; ozone. Sulphur – allotropic forms; compounds of sulphur: preparation, preparation, properties and uses of sulphur dioxide; sulphuric acid: industrial process of manufacture, properties and uses, oxoacids of sulphur (structures only)
- Group 17 elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens: preparation, properties and uses of chlorine and hydrochloric acid, interhalogen compounds oxoacids of halogens (structures only)
- Group 18 elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses
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Unit 8 | d and f Block Elements | - General introduction, electronic configuration, characteristics of transition metals, general trends in properties of the first row transition metals- metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation. Preparation and properties of K2Cr2O7 and KMnO4
- Lanthanoids- electronic configuration, oxidation states, chemical reactivity, and lanthanoid contraction and its consequences. Actinoids: Electronic configuration, oxidation states and comparison with lanthanoids
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Unit 9 | Coordination Compounds | Coordination compounds: Introduction, ligands, coordination number, colour, magnetic properties and shapes, IUPAC nomenclature of mononuclear coordination compounds, isomerism (structural and stereo) bonding, Werner’s theory VBT,CFT; importance of coordination compounds (in qualitative analysis, biological systems) |
Unit 10 | Haloalkanes and Haloarenes | - Haloalkanes: Nomenclature, nature of C –X bond, physical and chemical properties, mechanism of substitution reactions. Optical rotation
- Haloarenes: Nature of C-X bond, substitution reactions (directive influence of halogen for monosubstituted compounds only) Uses and environment effects of – dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT
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Unit 11 | Alcohols, Phenols and Ethers | - Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only); identification of primary, secondary and tertiary alcohols; mechanism of dehydration, uses with special reference to methanol and ethanol
- Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophilic substitution reactions, uses of phenols
- Ethers: Nomenclature, methods of preparation, physical and chemical properties uses
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Unit 12 | Aldehydes, Ketones and Carboxylic Acids | - Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties; and mechanism of nucleophilic addition, reactivity of alpha hydrogen in aldehydes; uses
- Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses
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Unit 13 | Organic Compounds Containing Nitrogen | - Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary secondary and tertiary amines.
- Cyanides and Isocyanides- will be mentioned at relevant places.
- Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.
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Unit 14 | Biomolecules | - Carbohydrates- Classification (aldoses and ketoses), monosaccharide (glucose and fructose), D.L. configuration, oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen): importance. Vitamins- Classification and function.
- Proteins- Elementary idea of – amino acids, peptide bond, polypeptides, proteins, primary structure, secondary structure, tertiary structure and quaternary structure (qualitative idea only), denaturation of proteins; enzymes. Hormones- Elementary idea (excluding structure). Nucleic Acids: DNA and RNA
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Unit 15 | Polymers | Classification- Natural and synthetic, methods of polymerization (addition and condensation), copolymerization. Some important polymers: natural and synthetic like polyesters, bakelite; rubber, Biodegradable and non-biodegradable polymers. |
Unit 16 | Chemistry in Everyday Life | - Chemicals in medicines- analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamines.
- Chemicals in food- preservatives, artificial sweetening agents, elementary idea of antioxidants.
- Cleansing agents- soaps and detergents, cleansing action.
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