DU regular colleges will be better for UPSC preparation. The syllabus for most courses matches with UPSC syllabus. If your aim is UPSC, choose your course accordingly. Opt for a subject, you are going to take as optional.
Being a regular student of DU, you will be able to attend seminars/discussions which can help a lot in personality development. Which is a major requirement for UPSE.
If you can manage regular classes along with UPSE preparation, choose DU regular.
Both DU SOL and DU are very good institutes to prepare for UPSC and both of them have their own advantages. Let me share some facts I got to know from the reviews.
Hence, both of them have their own set of advantages and you can choose any one of them depending upon your interests and requirements.