Two years ago, one of my friends was in the same situation. He could have taken electrical and sit for every company’s placements. If he chooses mechanical, then only core opportunities are open. Given the circumstances, he chose electrical in the first round of counseling. It was so because he would at least get a chance to sit in almost every business. 

Sitting in a good company does not guarantee a good job, and mechanical engineering at PEC is far superior to that of many NITs and even IITs. Trusting his seniors and teachers, he switched to mechanical on the spot round to which he doesn't regret till now. 

If you're interested in electrical, go for it. Since my friend had no particular interest in any of these subjects, he preferred mechanical over electrical.