Question:medium

The coagulating power of electrolytes having ions Na$^+$, Al$^{3+}$ and Ba$^{2+}$ for As$_2$S$_3$ sol increases in the order

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Key Points: 
As$_2$S$_3$ sol is negatively charged. 
Coagulation of negatively charged sols is caused by cations. 
Hardy-Schulze Rule: Coagulating power increases significantly with increasing charge magnitude of the coagulating ion. 
Cation Charges: Na$^{+}$ (+1), Ba$^{2+}$ (+2), Al$^{3+}$ (+3). 
Increasing Coagulating Power: Na$^{+}$ $<$ Ba$^{2+}$ $<$ Al$^{3+}$.

Updated On: Nov 28, 2025
  • Al$^{3+}$ $<$ Ba$^{2+}$ $<$ Na$^{+}$
  • Na$^{+}$ $<$ Ba$^{2+}$ $<$ Al$^{3+}$
  • Ba$^{2+}$ $<$ Na$^{+}$ $<$ Al$^{3+}$
  • Al$^{3+}$ $<$ Na$^{+}$ $<$ Ba$^{2+}$