For an undeflected motion of a charged particle in crossed electric and magnetic fields (\( \vec{E} \perp \vec{B} \)), the condition is \( \vec{E} = - (\vec{v} \times \vec{B} ) \), and the magnitude is \( E = v B \) when \( \vec{v} \perp \vec{B} \). The electric field must be perpendicular to both velocity and magnetic field.